#Magnesiumingot:Mg>99.95%impuritycontent:iron<0.002,silicon<0.009,aluminium<0.006,manganese<0.015,nickel<0.001,copper<0.005,totalimpurity<0.05%.
2Magnesiumingot:Mg99.9 impurity content Fe0.04 Si0.005 Al0.02 Mn0.03 Ni0.001 Cu0.004 impurity total 0.1%.
Magnesiumapplications:Mainlyconcentratedinmagnesiumalloyproduction,aluminumalloyproduction,steel-makingdesulfurization,aviationandmilitaryindustries,inadditiontorareearthalloys,metalreduction,chemicalindustryandinstrumentmanufacturingindustry.
|
Brand name |
Chemical constituents (mass fraction)/% |
|||||||||||
|
Mg≥ |
Impurity element≤ |
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|
Fe |
Si |
Ni |
Cu |
Al |
Mn |
Ti |
Pb |
Sn |
Zn |
其他 |
||
|
Mg9999 |
99.99 |
0.002 |
0.002 |
0.0003 |
0.002 |
0.002 |
0.002 |
0.0005 |
0.001 |
0.002 |
0.003 |
- |
|
Mg9998 |
99.98 |
0.002 |
0.003 |
0.0005 |
0.004 |
0.004 |
0.002 |
0.001 |
0.001 |
0.004 |
0.004 |
- |
|
Mg9995A |
99.95 |
0.003 |
0.006 |
0.001 |
0.002 |
0.008 |
0.006 |
- |
0.005 |
0.005 |
0.005 |
0.005 |
|
Mg9990B |
99.90 |
0.04 |
0.03 |
0.001 |
0.004 |
0.02 |
0.03 |
- |
- |
- |
- |
0.01 |
|
Mg9980 |
99.80 |
0.05 |
0.05 |
0.002 |
0.002 |
0.005 |
0.005 |
- |
- |
- |
- |
0.01 |
|
Cb,Hg,As,Cr6+Elements may not be routinely analyzed by suppliers, but their contents and requirements shall be monitored.(Cd+Hg+As+Cr)≤0.03% |
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Case Study
Background
A leading international manufacturer of aerospace-grade aluminum extrusions (seating tracks and wing stringers) faced persistent issues with tensile strength inconsistency and hydrogen porosity. Their existing magnesium ingot, used as an alloying addition (target: 4.0–4.5% Mg in 5083 alloy), showed variable dissolution behavior and high oxide inclusion levels, resulting in a 12% rejection rate during ultrasonic testing.
The Challenge
The customer required a magnesium ingot that delivers:
Consistent magnesium recovery (98–99.5%)
Ultra-low impurity limits (especially Fe, Cu, Ni for corrosion resistance)
Clean, oxide-free surface to prevent dross entrainment
Uniform dissolution without sparking or rapid oxidation
Solution
They switched to a high-purity magnesium ingot (99.95% Mg min.) with the following specifications:
Impurity control: Fe ≤0.002%, Cu ≤0.001%, Ni ≤0.0005%, Si ≤0.003%
Physical form: 7.5 kg tapered ingots, chamfered edges, bright metallic surface
Packaging: Vacuum-sealed aluminum foil + desiccant to prevent pre-oxidation
Implementation
The new ingots were introduced into the existing reverberatory furnace process:
Addition temperature: 720–740°C (under argon cover gas)
Addition method: Preheated ingots (150°C) submerged via bell tool
Holding time after addition: ≤20 minutes before casting
Comparative Results (30 production runs)
| Parameter | Standard Mg Ingot | High-Quality Mg Ingot | Improvement |
|---|---|---|---|
| Mg recovery | 94.2% | 99.1% | +5.2% |
| Iron content in alloy | 0.018% | 0.007% | -61% |
| Hydrogen porosity (X-ray) | Class B (3–5%) | Class A (<1%) | -75% |
| Tensile strength (MPa) | 285 ± 18 | 305 ± 6 | +7% (lower scatter) |
| Corrosion rate (ASTM G67) | 18 mg/cm²/day | 8 mg/cm²/day | -56% |
| Rejection rate | 12.3% | 1.8% | -85% |
Key Observations
Faster dissolution: High-quality ingots melted completely within 45 seconds vs. 90 seconds for standard grade, reducing furnace exposure time.
Reduced dross formation: Oxide-free surface cut dross generation by 60%, saving €120 per melt.
Consistent grain refinement: Uniform Mg distribution eliminated banding in final extrusions.
Extended furnace life: Lower chloride flux usage (due to cleaner ingots) doubled refractory lining life from 18 to 36 months.
Financial Impact
The aerospace customer calculated annual savings of €340,000:
€150,000 from reduced scrap and rework
€90,000 from lower dross handling and flux consumption
€100,000 from extended furnace maintenance intervals
Conclusion
By upgrading to high-quality magnesium ingot with rigorous purity control (99.95% Mg, Fe<20 ppm) and oxide-free surfaces, the manufacturer achieved:
Zero field failures in subsequent fatigue testing (10⁷ cycles)
AS9100D certification renewal with improved process capability (Cpk from 0.9 to 1.4)
Ability to competitively bid on new aerospace contracts requiring EN 573-3 compliance
Recommendation
For aluminum alloy producers targeting demanding sectors (aerospace, automotive, defense), high-quality magnesium ingot is not an added cost-it is an investment. The payback period for this switch was under 60 days, driven by recovery efficiency alone. Always demand certified mill test reports (MTRs) with actual trace element analysis, not typical ranges.
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